Primitive atmosphere was made up of mixture of 

The primitive atmosphere of earth was reducing atmosphere with little or no oxygen but was rich in water vapour, carbon monoxide, carbon dioxide, nitrogen and hydrogen. Thus, oxygen was not present in primitive atmosphere. The high temperature, UV light and lightening provided energy for chemical reactions between hydrogen and free oxygen, nitrogen and carbon to form, ammonia, methane and cyanides. Owing to the high temperature of earth, water was present in form of superheated steam and ammonia, methane and cyanides were present in gaseous form.